Proof.
Note that any finite purely inseparable extension k'/k embeds in k^{perf}. Moreover, k^{1/p} embeds into k^{perf} which embeds into \overline{k}. Thus it is clear that (5) \Rightarrow (4) \Rightarrow (3) \Rightarrow (2) and that (3) \Rightarrow (1).
We prove that (1) \Rightarrow (5). Assume k' \otimes _ k S is reduced for every finite purely inseparable extension k' of k. Let K/k be an extension of fields. We have to show that K \otimes _ k S is reduced. By Lemma 10.43.4 we reduce to the case where K/k is a finitely generated field extension. Choose a diagram
\xymatrix{ K \ar[r] & K' \\ k \ar[u] \ar[r] & k' \ar[u] }
as in Lemma 10.42.4. By assumption k' \otimes _ k S is reduced. By Lemma 10.43.6 it follows that K' \otimes _ k S is reduced. Hence we conclude that K \otimes _ k S is reduced as desired.
Finally we prove that (2) \Rightarrow (5). Assume k^{1/p} \otimes _ k S is reduced. Then S is reduced. Moreover, for each localization S_{\mathfrak p} at a minimal prime \mathfrak p, the ring k^{1/p}\otimes _ k S_{\mathfrak p} is a localization of k^{1/p} \otimes _ k S hence is reduced. But S_{\mathfrak p} is a field by Lemma 10.25.1, hence S_{\mathfrak p} is geometrically reduced by Lemma 10.44.2. It follows from Lemma 10.43.7 that S is geometrically reduced.
\square
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