Proof.
Proof of (1). We may replace X, Y, S by suitable affine open neighbourhoods of x, y, s and reduce to the following algebra problem: given a ring R, two R-algebra maps \varphi , \psi : B \to A such that
R \to B is of finite type, or A is a domain, or A is Noetherian, or A is reduced and has finitely many minimal primes,
the two maps B \to A_\mathfrak p are the same for some prime \mathfrak p \subset A,
show that \varphi , \psi define the same map B \to A_ g for a suitable g \in A, g \not\in \mathfrak p. If R \to B is of finite type, let t_1, \ldots , t_ m \in B be generators of B as an R-algebra. For each j we can find g_ j \in A, g_ j \not\in \mathfrak p such that \varphi (t_ j) and \psi (t_ j) have the same image in A_{g_ j}. Then we set g = \prod g_ j. In the other cases (if A is a domain, Noetherian, or reduced with finitely many minimal primes), we can find a g \in A, g \not\in \mathfrak p such that A_ g \subset A_\mathfrak p. See Algebra, Lemma 10.31.9. Thus the maps B \to A_ g are equal as desired.
Proof of (2). To do this we may replace X, Y, and S by suitable affine opens. Say X = \mathop{\mathrm{Spec}}(A), Y = \mathop{\mathrm{Spec}}(B), and S = \mathop{\mathrm{Spec}}(R). Let \mathfrak p \subset A be the prime ideal corresponding to x. Let \mathfrak q \subset B be the prime corresponding to y. Then \varphi is a local R-algebra map \varphi : B_\mathfrak q \to A_\mathfrak p. If R \to B is a ring map of finite presentation, then there exists a g \in A \setminus \mathfrak p and an R-algebra map B \to A_ g such that
\xymatrix{ B_\mathfrak q \ar[r]_\varphi & A_\mathfrak p \\ B \ar[u] \ar[r] & A_ g \ar[u] }
commutes, see Algebra, Lemmas 10.127.3 and 10.9.9. The induced morphism \mathop{\mathrm{Spec}}(A_ g) \to \mathop{\mathrm{Spec}}(B) works. If B is of finite type over R, let t_1, \ldots , t_ m \in B be generators of B as an R-algebra. Then we can choose g_ j \in A, g_ j \not\in \mathfrak p such that \varphi (t_ j) \in \mathop{\mathrm{Im}}(A_{g_ j} \to A_\mathfrak p). Thus after replacing A by A[1/\prod g_ j] we may assume that B maps into the image of A \to A_\mathfrak p. If we can find a g \in A, g \not\in \mathfrak p such that A_ g \to A_\mathfrak p is injective, then we'll get the desired R-algebra map B \to A_ g. Thus the proof is finished by another application of See Algebra, Lemma 10.31.9.
\square
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