Proof.
By definition of degree and genus we have
\dim _ k H^0(X, \mathcal{L}) - \dim _ k H^1(X, \mathcal{L}) = d + 1
Let s be a nonzero section of \mathcal{L}. Then the zero scheme of s is an effective Cartier divisor D \subset X, we have \mathcal{L} = \mathcal{O}_ X(D) and we have a short exact sequence
0 \to \mathcal{O}_ X \to \mathcal{L} \to \mathcal{L}|_ D \to 0
see Divisors, Lemma 31.14.10 and Remark 31.14.11. Since H^1(X, \mathcal{O}_ X) = 0 by assumption, we see that H^0(X, \mathcal{L}) \to H^0(X, \mathcal{L}|_ D) is surjective. As \mathcal{L}|_ D is generated by global sections (because \dim (D) = 0, see Varieties, Lemma 33.33.3) we conclude that the invertible module \mathcal{L} is generated by global sections. In fact, since D is an Artinian scheme we have \mathcal{L}|_ D \cong \mathcal{O}_ D1 and hence we can find a section t of \mathcal{L} whose restriction of D generates \mathcal{L}|_ D. The short exact sequence also shows that H^1(X, \mathcal{L}) = 0.
For n \geq 1 consider the multiplication map
\mu _ n : H^0(X, \mathcal{L}) \otimes _ k H^0(X, \mathcal{L}^{\otimes n}) \longrightarrow H^0(X, \mathcal{L}^{\otimes n + 1})
We claim this is surjective. To see this we consider the short exact sequence
0 \to \mathcal{L}^{\otimes n} \xrightarrow {s} \mathcal{L}^{\otimes n + 1} \to \mathcal{L}^{\otimes n + 1}|_ D \to 0
The sections of \mathcal{L}^{\otimes n + 1} coming from the left in this sequence are in the image of \mu _ n. On the other hand, since H^0(\mathcal{L}) \to H^0(\mathcal{L}|_ D) is surjective and since t^ n maps to a trivialization of \mathcal{L}^{\otimes n}|_ D we see that \mu _ n(H^0(X, \mathcal{L}) \otimes t^ n) gives a subspace of H^0(X, \mathcal{L}^{\otimes n + 1}) surjecting onto the global sections of \mathcal{L}^{\otimes n + 1}|_ D. This proves the claim.
Observe that \mathcal{L} is ample by Varieties, Lemma 33.44.14. Hence Morphisms, Lemma 29.43.17 gives an isomorphism
X \longrightarrow \text{Proj}\left( \bigoplus \nolimits _{n \geq 0} H^0(X, \mathcal{L}^{\otimes n})\right)
Since the maps \mu _ n are surjective for all n \geq 1 we see that the graded algebra on the right hand side is a quotient of the symmetric algebra on H^0(X, \mathcal{L}). Choosing a k-basis s_0, \ldots , s_ d of H^0(X, \mathcal{L}) we see that it is a quotient of a polynomial algebra in d + 1 variables. Since quotients of graded rings correspond to closed immersions of \text{Proj} (Constructions, Lemma 27.11.5) we find a closed immersion X \to \mathbf{P}^ d_ k. We omit the verification that this morphism is the morphism of Constructions, Lemma 27.13.1 associated to the sections s_0, \ldots , s_ d of \mathcal{L}.
\square
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