Proof.
By the result of Lemma 42.67.9 we obtain a system of cycle groups Z_ k(X_ i) and a system of chow groups \mathop{\mathrm{CH}}\nolimits _ k(X_ i) as well as maps \mathop{\mathrm{colim}}\nolimits Z_ k(X_ i) \to Z_ k(X') and \mathop{\mathrm{colim}}\nolimits \mathop{\mathrm{CH}}\nolimits _ i(X_ i) \to \mathop{\mathrm{CH}}\nolimits _ k(X'). We may replace S by a quasi-compact open through which X \to S factors, hence we may and do assume all the schemes occurring in this proof are Noetherian (and hence quasi-compact and quasi-separated).
Let us show that the map \mathop{\mathrm{colim}}\nolimits Z_ k(X_ i) \to Z_ k(X') is surjective. Namely, let Z' \subset X' be an integral closed subscheme of \delta '-dimension k. By Limits, Lemma 32.10.1 we can find an i and a morphism Z_ i \to X_ i of finite presentation whose base change is Z'. After increasing i we may assume Z_ i is a closed subscheme of X_ i, see Limits, Lemma 32.8.5. Then Z' \to X_ i factors through Z_ i and we may replace Z_ i by the scheme theoretic image of Z' \to X_ i. In this way we see that we may assume Z_ i is an integral closed subscheme of X_ i. By Lemma 42.67.2 we conclude that \dim _{\delta _ i}(Z_ i) = \dim _{\delta '}(Z') = k. Thus Z_ k(X_ i) \to Z_ k(X') maps [Z_ i] to [Z'] and we conclude surjectivity holds.
Let us show that the map \mathop{\mathrm{colim}}\nolimits Z_ k(X_ i) \to Z_ k(X') is injective. Let \alpha _ i = \sum n_ j[Z_ j] \in Z_ k(X_ i) be a cycle whose image in Z_ k(X') is zero. We may and do assume Z_ j \not= Z_{j'} if j \not= j' and n_ j \not= 0 for all j. Denote Z'_ j \subset X' the base change of Z_ j. By Lemma 42.67.2 each irreducible component of Z'_ j has \delta '-dimension k. Moreover, as Z_ j is irreducible and Z'_ j \to Z_ j is flat (as the base change of S' \to S) we see that Z'_ j \to Z_ j is dominant. Hence if Z'_ j is nonempty, then some irreducible component, say Z', of Z'_ j dominates Z_ j. It follows that Z' cannot be an irreducible component of Z'_{j'} for j' \not= j. Hence if Z'_ j is nonempty, then we see that (S' \to S_ i)^*\alpha _ i = \sum [Z'_ j]_ r is nonzero (as the coefficient of Z' would be nonzero). Thus we see that Z'_ j = \emptyset for all j. However, this means that the base change of Z_ j by some transition map S_{i'} \to S_ i is empty by Limits, Lemma 32.4.3. Thus \alpha _ i dies in the colimit as desired.
The surjectivity of \mathop{\mathrm{colim}}\nolimits Z_ k(X_ i) \to Z_ k(X') implies that \mathop{\mathrm{colim}}\nolimits \mathop{\mathrm{CH}}\nolimits _ k(X_ i) \to \mathop{\mathrm{CH}}\nolimits _ k(X') is surjective. To finish the proof we show that this map is injective. Let \alpha _ i \in \mathop{\mathrm{CH}}\nolimits _ k(X_ i) be a cycle whose image \alpha ' \in \mathop{\mathrm{CH}}\nolimits _ k(X') is zero. Then there exist integral closed subschemes W_ l' \subset X', l = 1, \ldots , r of \delta "-dimension k + 1 and nonzero rational functions f'_ l on W'_ l such that \alpha ' = \sum _{l = 1, \ldots , r} \text{div}_{W'_ l}(f'_ l). Arguing as above we can find an i and integral closed subschemes W_{i, l} \subset X_ i of \delta _ i-dimension k + 1 whose base change is W'_ l. After increasing i we may assume we have rational functions f_{i, l} on W_{i, l}. Namely, we may think of f'_ l as a section of the structure sheaf over a nonempty open U'_ l \subset W'_ l, we can descend these opens by Limits, Lemma 32.4.11 and after increasing i we may descend f'_ l by Limits, Lemma 32.4.7. We claim that
\alpha _ i = \sum \nolimits _{l = 1, \ldots , r} \text{div}_{W_{i, l}}(f_{i, l})
after possibly increasing i.
To prove the claim, let Z'_{l, j} \subset W'_ l be a finite collection of integral closed subschemes of \delta '-dimension k such that f'_ l is an invertible regular function outside \bigcup _ j Y'_{l, j}. After increasing i (by the arguments above) we may assume there exist integral closed subschemes Z_{i, l, j} \subset W_ i of \delta _ i-dimension k such that f_{i, l} is an invertible regular function outside \bigcup _ j Z_{i, l, j}. Then we may write
\text{div}_{W'_ l}(f'_ l) = \sum n_{l, j} [Z'_{l, j}]
and
\text{div}_{W_{i, l}}(f_{i, l}) = \sum n_{i, l, j} [Z_{i, l, j}]
To prove the claim it suffices to show that n_{l, i} = n_{i, l, j}. Namely, this will imply that \beta _ i = \alpha _ i - \sum \nolimits _{l = 1, \ldots , r} \text{div}_{W_{i, l}}(f_{i, l}) is a cycle on X_ i whose pullback to X' is zero as a cycle! It follows that \beta _ i pulls back to zero as a cycle on X_{i'} for some i' \geq i by an easy argument we omit.
To prove the equality n_{l, i} = n_{i, l, j} we choose a generic point \xi ' \in Z'_{l, j} and we denote \xi \in Z_{i, l, j} the image which is a generic point also. Then the local ring map
\mathcal{O}_{W_{i, l}, \xi } \longrightarrow \mathcal{O}_{W'_ l, \xi '}
is flat as W'_ l \to W_{i, l} is the base change of the flat morphism S' \to S_ i. We also have \mathfrak m_\xi \mathcal{O}_{W'_ l, \xi '} = \mathfrak m_{\xi '} because Z_{i, l, j} pulls back to Z'_{l, j}! Thus the equality of
n_{l, j} = \text{ord}_{Z'_{l, j}}(f'_ l) = \text{ord}_{\mathcal{O}_{W'_ l, \xi '}}(f'_ l) \quad \text{and}\quad n_{i, l, j} = \text{ord}_{Z_{i, l, j}}(f_{i, l}) = \text{ord}_{\mathcal{O}_{W_{i, l}, \xi }}(f_{i, l})
follows from Algebra, Lemma 10.52.13 and the construction of \text{ord} in Algebra, Section 10.121.
\square
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